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Number one seed Williams, 33, who is the heavy favorite to win the tournament.
“No one wants it more than me” Serena Williams fires out warning to Australian Open rivals.
Williams has won the Australian Open five times but not since 2010.
"I remember last year I felt really good, was playing well," she said.
"I was feeling amazing on the court. This year I feel a little off. But I feel off in every Grand Slam - except for last year. That didn't work out for me, so maybe this is different."
Tournament starts 11pm UK time.